KAIST Vision Hall
Important On-campus Websites
Personal Information Policy
Main Campus (Daejeon)
Seoul Campus (Seoul)
Munji Campus (Daejeon)
Dogok Campus (Seoul)
How to get to KAIST
Giving to KAIST
Excellence in KAIST
Use of Gift
Make a Gift
College of Natural Sciences
College of Life Science and Bio Engineering
College of Engineering
College of Liberal Arts and Convergence Science
College of Business
School of Transdisciplinary Studies
General Studies Requirements
Education Support Program
Int'l Exchange Programs
International Scholar and Student Service Team
Center for Excellence in Learning and Teaching
Research Areas and Main Research Programs
Person in Charge by Research Area
Common Utilized Equipment
Office of Univ. Industry Coop.
World Economic Forum
KAIST Annual R&D Report
Student Health Insurance Association
Cultural Event Info.
Satisfaction survey of food&beverage Enterprise inside Campus
Day Care Center
Student Clubs and Activities
Undergraduate Student Clubs
Graduate Student Clubs
Center For Ethics And Human Rights
Intl’ Student Identity Card (ISIC)
KAIST in Media
International Scholar and Student Services
Producing 50x More Stable Adsorbent
(From left: Professor Minkee Choi and PhD candidate Woosung Choi)
A KAIST research team developed a technology to increase the stability of amine-containing adsorbents by fifty times, moving one step further toward commercializing stable adsorbents that last longer.
Professor Minkee Choi from the Department of Chemical and Biomolecular Engineering and his team succeeded in developing amine-containing adsorbents that show high oxidative stability.
The capture of the greenhouse gas carbon dioxide is an active ongoing research field, and some of the latest advancements point to amine-containing adsorbents as an efficient and environment-friendly way to capture carbon dioxide. However, existing amine-containing adsorbents are known to be unstable under oxidation, which chemically breaks down the adsorbent, thereby making it difficult to rely on amine-containing adsorbents for repeated and continued use.
The researchers have discovered that the miniscule amount of iron and copper present in the amine accelerate the oxidative breakdown of the amine-containing adsorbent. Upon this discovery, they proposed the use of a chelator substance, which essentially suppresses the activation of the impurities.
The team demonstrates that the proposed method renders the adsorbent up to 50 times slower in its deactivation rate due to oxidation, compared to conventional polyethyleneimine (PEI) / silica adsorbents. Figure 1 illustrates the superior performance of this oxidation-stable amine-containing adsorbent (shown in black squares), whose carbon dioxide-capturing capacity deteriorates by only a small amount (~8%). Meanwhile, the carbon dioxide-capturing capacity of the PEI/silica adsorbent (shown in red diamonds) degrades dramatically after being exposed to oxidative aging for 30 days.
This stability under oxidation is expected to have brought amine-containing adsorbents one step closer to commercialization. As such, first author Woosung Choi describes the significance of this study as “having brought solid carbon dioxide adsorbents to commercializable standards”. In fact, Professor Choi explains that commercialization steps for his team’s carbon dioxide adsorbents are already underway. He further set forth his aim to “develop the world’s best carbon dioxide capture adsorbent”.
This research, led by the PhD candidate Woosung Choi, was published online in Nature Communications on February 20.
Figure 1. Carbon dioxide working capacity against oxidative aging time. Performance of the proposed method (black) degrades much more slowly (~50x) than that of existing methods. The novel adsorbent is thus shown to be more robust to oxidation.